Gold coins are often sold as bullion coins, but not always.  Gold coins have a known purity and weight.  Most gold coins currently being minted have a purity of 0.999 or 0.9999.  These coins are considered 24-karat gold, or fine gold.  Expectation that these will be worth the value of gold is reasonable, provided you allow for a slight reduction of value when selling to a dealer, and a slight increase of value when buying from a dealer. 
 
Some gold coins, including the United States American Eagle and the British Gold Sovereign, are 22-karat coins, which means their purity is 0.9167 pure.  While more is often better, if the gold is to be used as gold for jewelry making, the 22-karat gold is actually a purity that is right for jewelry making.  Also, the British Gold Sovereign is a well-respected coin, and has a stellar reputation.  The United States Gold Eagle has appeal to collectors in the United States.
 
If a coin is not 0.999 gold or even of greater purity, know the AGW (Actual gold weight) before making your decision.
 
Comments
Gold can be quite thin, probably just a few molecules thick. Think about a piece that is selectively gold plated, it is not really obvious the gold makes the piece slightly thicker where it is placed. Think microns, millionths of a meter, or smaller.
blackspanielgallery, Thank you for the practical information and product lines.
How thin is the layer of gold-plating on the 10-foot by 10-foot by 10-foot cube room?